By Prigogine I.
The matter of time in physics and chemistry is heavily with regards to the formula of the second one legislations of thermodynamics. for that reason one other attainable identify of this lecture might have been: "the macroscopic and microscopic facets of the second one legislations of thermodynamics".
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Time, structure and fluctuations
The matter of time in physics and chemistry is heavily concerning the formula of the second one legislation of thermodynamics. accordingly one other attainable name of this lecture might have been: "the macroscopic and microscopic facets of the second one legislations of thermodynamics".
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When a droplet is found on a surface two contradictory mechanisms are observed. The attraction forces between the droplet molecules, which action is in favor of the droplet surface decrease (form of minimum energy) and the surface tension in the direction of the droplet dispersion. The equilibrium usually achieved is described by the Young equation and especially the value of the contact angle θ. 2. This is the result of the weak intermolecular attractions observed between the silicone rubber molecules, although the molecule structure (backbone) is remarkably stronger (silicon–oxygen bond) in comparison to the other polymeric materials used for outdoor insulation.
Prentice Hall, Englewood Cliff, NJ, USA, p. 309, 1993. 17. G. Belorgey and G. G.
The speed of recovery and the endurance of the migration mechanism are affected from the amount of LMW molecules available. The initial population and type (linear or cyclic) depends on the polymerization process and the vulcanization that follows. Further, during service a possible loss of the LMW molecules can be assumed since they are exposed on the surface. Consequently, a probable depletion of the LMW reservoir, which corresponds to the end of the material lifetime, becomes the primary user concern, and thus the parameters that influence the diffusion process have to be considered.