By Alfred Rudin
Answer handbook for the weather of Polymer technology and Engineering
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Additional info for Solutions Manual for the Elements of Polymer Science and Engineering
Sample text
In An a l t e r n a t i v e procedure would involve a d d i t i o n of chain t r a n s f e r agents but the d e t a i l s of such 33 7-5. (Cont'd) procedures cannot be q u a n t i f i e d without knowledge of the nature of the polymerizing monomer and reaction temperature. Since this information was not provided the only way the question can be answered i n general i s as o u t l i n e d . 7-6. The enhanced polymerization rate probably r e f l e c t s the existence of more than one r a d i c a l per p a r t i c l e because of the large size.
Since [I]. 45 (Cont'd) Since the napthalene is i n excess the t o t a l no. 043 moles. The no. 6 χ 10 moles. T o t a l volume of the polymerization mixture « 50 mi + 1 mi. • 51 a * . 0169 Μ. 1 I From eq. 6 (DP ) Μ n o (1-2) ( 1 1 3 . 01 ( 1 . 0 1 ) ( 1 1 , 8 0 0 ) - 11,900. 46 Chapter 10 10-1. 34 ( 1 . 4 0 ) (300) - 422. 42 0 . 6 6 K 2( 2 8 0 ) . The volume of che head space i n the p o l y m e r i z a t i o n reactor above the polymer melt i s independent of temperature. The vapor pressure (1 atm steam) also does noc vary w i t h temperature.
4 0 ( 0 . 4 0 + 1 . 25) + ( 0 . 25) + 2 ( 0 . 2 5 ) + 1 4 . 3 ( 0 . 06. It I s not a good I d e a . The reaction w i l l not y i e l d copolymers w i t h appreciable concentrations of both monomers. 8-9. For a random copolymerization r ^ r 2 - 1. 32 • mole f r a c t i o n of ethylene i n the gas phase. Gas phase composition • 32 mole Ζ ethylene and 68 mole Ζ propylene, r f 8-10. 65(1 - f x) 2 ( 8 39 8-10. 05f* + 0 . 3525f^ + 0 . 6175 - 0 . 931 ( p o s i t i v e Conclusion: root). 069 mole f r a c t i o n v i n y l acetate) i n the feed.