By Jian Zhou
This booklet introduces multi-catalyst platforms by means of describing their mechanism and merits in uneven catalysis.
• Helps natural chemists practice extra effective catalysis with step by step methods
• Overviews new strategies and development for greener and financial catalytic reactions
• Covers subject matters of curiosity in uneven catalysis together with bifunctional catalysis, cooperative catalysis, multimetallic catalysis, and novel tandem reactions
• Has functions for prescribed drugs, agrochemicals, fabrics, and flavour and perfume
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Mohr, M. R. Krout, and B. M. Stoltz. -U. Blaser, Chem. Commun. 2003, 293–296. [19] (a) T. Bui, S. Syed, and C. F. Barbas III. J. Am. Chem. Soc. 2009, 131, 8758–8759; For the simultaneously independent work realized by chiral Lewis acid catalysis: (b) Y. Kato, M. Furutachi, Z. Chen, H. Mitsunuma, S. Matsunaga, and M. Shibasaki, J. Am. Chem. Soc. 2009, 131, 9168–9169. [20] For a discussion, see: (a) F. -L. Liu, and J. Zhou. Adv. Synth. Catal. 2010, 352, 1381–1407; (b) M. Ding, F. -L. -H. -L. Zhao, and J.
Another convincing example to demonstrate the exceptional power of the discovery of new activation models to realize ideal asymmetric catalysis is the evolution of asymmetric Diels–Alder reaction, which is probably the most powerful organic reaction in chemical synthesis, allowing facile construction of substituted carbocycles from simple substrates [56]. While notable progress has been made in the development of chiral Lewis acid catalyzed asymmetric Diels–Alder reaction using reactive cyclopentadiene, the corresponding process using less reactive dienes such as 1,3cyclohexadiene and heavily substituted acyclic dienes proves to be very challenging.
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