By Zaikov, Gennady
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In this case, a facile reaction occurred. On the basis of theoretical as well as kinetic and product studies, the reactions were interpreted as proceeding through attack of one IV at the carbonyl carbon, forming an A-acyl radical intermediate. 26) The adducts of ARs with organic free radicals have attracted considerable attention because of their potential utility as free radical initiators, and because of the important role of reversible dissociation of adducts of IV in living radical polymerisation.