By Michael Faraday
This can be a facsimile reprint of Faraday's unique ebook released in 1895 by means of Taylor and Francis, which used to be a suite of his papers written over a interval of forty years and released in quite a few discovered and medical journals akin to "Philosophical Magazine", "Philosophical Transactions of the Royal Society" and "The magazine of the Royal Institution". The e-book is meant to have fun the bicentenniel of Faraday's Read more...
summary: this can be a facsimile reprint of Faraday's unique ebook released in 1895 via Taylor and Francis, which used to be a set of his papers written over a interval of forty years and released in a variety of realized and medical journals comparable to "Philosophical Magazine", "Philosophical Transactions of the Royal Society" and "The magazine of the Royal Institution". The ebook is meant to have a good time the bicentenniel of Faraday's start in 1791
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360. Experimental researches in chemistry and physics 24 even when no acid is present, and that thus hydrogen is still the agent. But I find that zinc decomposes chloride of silver even more rapidly when unembarrassed by water, than when water is present. Thus, if a little fused chloride of silver and a small portion of zinc be heated in a glass tube, a violent action takes place; chloride of zinc is formed and silver liberated, and the heat rises so high as generally to fuse the silver; or if dry chloride of silver in powder be triturated in a mortar with zinc filings, the two bodies immediately act, and a heat above that of boiling water is produced.
I have also often observed the formation of the crystals in retorts in common daylight. 5 cubic inches more of chlorine were passed in, and the retort set aside in a dark place for two days. At the end of that time muriatic acid gas and the solid chloride had formed, but the greater part of the fluid remained unchanged. Hence it will form even in the dark by length of time. Experimental researches in chemistry and physics 28 I tried to produce the chloride by exposure of the two gases in tubes over water to strong lamp-light for two or three hours, but could not succeed.
A portion of olefiant gas was then mixed in a retort with eight or nine times its bulk of chlorine, and exposed to sunlight. At first the fluid formed, but this instantly disappeared; the retort became lined with crystals, and the colour of the chlorine very much diminished. On examining these crystals, I found they were the compound I was in search of; but before I give the proofs of their nature, I will describe the process by which this chloride of carbon can be obtained pure. —A glass vessel was made in the form of an alembic head, but without the beak; the neck was considerably contracted, and had a brass cap with a stopcock cemented on; at the top was a small aperture, into which a ground stopper fitted air-tight.