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Extra resources for Encyclopedia of Electrochemistry, Volume 7a: Inorganic Electrochemistry (Encyclopedia of Electrochemistry)
81 V  (Formal potentials of metal hexacyanoferrates can be found in Ch. 8 V The aqua complexes of Fe2+ and Fe3+ , which are present in acid solutions, can hydrolyze to FeOH+ , Fe(OH)2+ , Fe(OH)2 + , and other ions at higher pH values, and the respective hydroxides precipitate. Weak anion complexes such as FeSO4 , FeSO4 + , or FeCl2+ can also be formed. 07 Ru), OS: +8, +7, +6, 44 +4, +3, +2, 0; IE: 711 kJ mol−1 . 99 V (calcd) RuO4 − (aq) + 3e− + 4H+ −−−→ RuO2 (s, hydr) + 2H2 O The formation of polymeric and mixedvalence complexes also occurs in aqueous solutions.
324 × 10−3 g. Solubility of ammonia in 100 g water at 1 bar and 20 ◦ C is 54 g. 9739 15 P), OS: +5, +4, +3, +2, +1, 0, −1/3, −1, −2, −3; IE: 1402, 2856, 4577 kJ mol−1 , 16920 (IV + V) kJ mol−1 . 89 V 59 60 2 Standard, Formal, and Other Characteristic Potentials of Selected Electrode Reactions The majority of the E 0 values are calculated from thermodynamic values. 921 33 As), OS: +7, +5, +3, (+2), (+1), 0, (−1), −3; IE: 947, 1798, 2736 kJ mol−1 , 10 880 (IV + V) kJ mol−1 . 37 V Most of the E 0 values are calculated from thermodynamic data.
333 V (calcd)  ( 107 Bh) Bohrium No data are available. 845 Fe), OS: (+6), +3, +2, 0; IE: 26 759 kJ mol−1 . 348 V versus SHE(aq) (CH3 CN) The formal potential of the substituted ferrocenes can be found in Ref. 38. 81 V  (Formal potentials of metal hexacyanoferrates can be found in Ch. 8 V The aqua complexes of Fe2+ and Fe3+ , which are present in acid solutions, can hydrolyze to FeOH+ , Fe(OH)2+ , Fe(OH)2 + , and other ions at higher pH values, and the respective hydroxides precipitate.