By Ronald A. McCauley
''This well known ebook is helping readers handle corrosion difficulties and create the main corrosion-resistant platforms attainable. It examines corrosion by means of gases, beverages, and solids and provides a number of types for comparing corrosion. Now appropriate as a graduate-level textual content, this extended and entirely reorganized 3rd variation contains numerous new chapters in addition to contemporary literature and examine findings. New chaptersRead more...
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Extra info for Corrosion of ceramic materials
Sample text
Cavernous weathering is a process thatstructure leaves theissurface of the rock of pits in a honeycomb-like * This structure. believed to be thefull result of repeated salt solution penetration, reaction and/or dissolution of various mineral species, drying associated with transport to the surface, and crystallization. This process is similar to if not identical to what is called efflorescence described above. In efflorescence the surface crystallization remains as a whitish deposit rather than being eroded or dissolved away.
Thus it is a question of whether or not the chromium will be oxidized while in the landfill and whether or not this oxidized ion will be leached into the surrounding ground waters. At present there still has not been a definitive study performed to determine accurately the fate of the chromium in these materials. Today an extremely important area of corrosion problems related to weathering is that of historic buildings, monuments, and landmarks. The civil engineering community has made great strides in recent years in understanding the mechanisms of weathering of ancient building materials.
Electronic conductivity, which is related to the oxide structure and bonding, is more important the greater the covalent character of the oxide. In chemical dissolution, crystallographic and metal-oxygen bond strengths play a very important role; whereas in electrochemical dissolution the electronic structure is of prime importance. Dissolution of solids in solutions is sometimes dependent upon surface controlled reactions at the solid/solution interface. The exchange rate between the solid and the solution ligands decreases as the cation charge increases, forming stronger bonds between the cation and the ligands.