Content:
Chapter 1 common and theoretical elements of the COOH and COOR teams (pages 1–52): Massimo Simonetta and Sergio Carra
Chapter 2 Electrochemical reactions of carboxylic acids and comparable tactics (pages 53–101): Lennart Eberson
Chapter three Alcoholysis, acidolysis and redistribution of esters (pages 103–136): Jouko Koskikallio
Chapter four The formation of carboxylic acids and their derivatives from organometallic compounds (pages 137–173): R. P. A. Sneeden
Chapter five Synthesis of di? and polycarboxylic acids and esters (pages 175–209): V. F. Kucherov and L. A. Yanovskaya
Chapter 6 Acidity and hydrogen bonding of carboxyl teams (pages 211–293): Lennart Eberson
Chapter 7 advent of COOH teams through carbonyl olefination (pages 295–340): L. D. Bergelson and M. M. Shemyakin
Chapter eight Rearrangement and cyclization reactions of carboxylic acids and esters (pages 341–373): Harold Kwart and Kenneth King
Chapter nine Substitution within the teams COOH and COOR (pages 375–452): D. P. N. Satchell and R. S. Satchell
Chapter 10 Syntheses and makes use of of isotopically labelled carboxylic acids (pages 453–503): Mieczyslaw Zielinski
Chapter eleven Esterification and ester hydrolysis (pages 505–588): Erkki ok. Euranto
Chapter 12 The decarboxylation response (pages 589–622): Louis W. Clark
Chapter thirteen Ortho esters (pages 623–667): E. H. Cordes
Chapter 14 Peracids and peresters (pages 669–703): Sven?Olov Lawesson and Gustav Schroll
Chapter 15 Thiolo, thiono and dithio acids and esters (pages 705–764): Matthys J. Janssen
Chapter sixteen Directive and activating results of CO2H and CO2R teams in fragrant and aliphatic reactions (pages 765–869): G. Kohnstam and D. L. H. Williams
Chapter 17 research of carboxylic acids and esters (pages 871–921): T. S. Ma
Chapter 18 organic formation and reactions of the ?COOH and ?COOR teams (pages 923–1064): Shawn Doonan
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Extra resources for Carboxylic Acids and Esters (1969)
Sample text
Fhys.. 31 1 (1956). 142. J. Donohue, J. Pliys. 502 (1952). 143. W. Fuller, J. Phys. , 63. 1705 ( 1959). i44. K. Nakamoto, M. Margoshes and R. E. Rundle. J. Am. Cliem. ,77, 6480 ( 1 955). 145. Pimentcl and C. H. Sederholm, J. Cliem. , 24,639 (1956). 146. J. Hermans, S. J. A. Sheraga. J. A m . Cliem. ,85, 1390 (1963). 147. C. A. Coulson, Reseurcli, 10, 149 ( I 957). 148. J. A. Pople, Proc. Roy. (London). A 205, 163 (1951). 149. Tsubomura, Bull. Chem. Japan, 27,445 (1954). 150. N. Coggeshall, J. , 18,978(1950).
R. spectra of l i 0 carboxylic acids and esters show the presence of a single absorption band'". 8 10 FIGURE 13. Concentration dependence of the chemical shift 6 of proton magnetic resonance of acetic acid in aqueous solution: p, is the proton fraction in the acid. and 7b. Some characteristic ''0 chemical shifts are shown in Table 21. TABLE 21. Some characteristic ''0chemical shifts in carboxylic acids and esters - . rn. from water) -_ - 130 to - 160 to -240 to -350 to - 150 - 180 -260 -370 Compounds .
B. Grasso and S. Pignataro, Mof. , 11,221 (1966). 136. C. Moser, J . Chem. , 1073(1953). 137. J. M. Skinner, G. M. D. Stewart and J. C. Speakman, J . Cliem. ,180 (1954). 138. H. C. Longuet-Higgins and J. N. Murrcll, Proc. Phys. A 68, 601 (1955). 139. Kon, Bull. Clirm. Japan, 28,275 (1955). 140. R. Pariser and R. G. Parr, J . Chem. 767 ( I 953). 141. J. Tanaka. S. Nagakura and M. Kobayashi, J . Chem. fhys.. 31 1 (1956). 142. J. Donohue, J. Pliys. 502 (1952). 143. W. Fuller, J. Phys. , 63. 1705 ( 1959).